Valorization of cashew nut shells as a binder for paint

LEMAIRE Marc, RAFANOELA Sandratriniaina Hermann, RANARIJAONA Miarintsoa Michaële, RAMIHARIMANANA Fenia Diane, ANDRIANJAFY Mbolatiana Tovo

Résumé

Actually, manufacturers are committed to developing bio-based products in order to replace fossil-based products with greater environmental impact. The International Associated Laboratory of the University of Antananarivo/University of Lyon1 is developing sustainable chemistry as one of its main research area. One of the examples in this field is the processing of cashew nut shell oil (CNSL) which is the main waste product of cashew nuts.   The extraction of CNSL was realized using butyl acetate as a solvent. Binder synthesis was then carried out from this cashew nut shell liquid (CNSL) using potassium hydroxide and sodium chloroacetate in solution in order to obtain the oxyacetic derivative of CNSL. The latter was used as a binder in our paint and varnishes formulations. The material obtained as stable, free from any organic solvent (100% "water born") and didn’t require the use of drying agent or toxic additives. Weather resistance is estimated at over two years.

cashew nut shell oil, oxyacetic acid, bio-sourced, binder, paint

Texte intégral

PDF

References

 [1]. Nour MATTAR. (2021). « Matériaux composites biosourcés pour la construction durable » Docteur en Sciences, Ingénierie et Environnement. Université Paris-Est.p.206

[2]. M. CHERIA, L. KEFF, R. PRUNIAUX, 22 Janvier 2020 « Les peintures biosourcées »,

 [3]. Miarintsoa Michaele RANARIJAONA, (2021). « Valorisation de coques de Noix de Cajou de Madagascar en liants pour peinture et Surfactants », Docteur en Ressources des Ressources Naturelles Renouvelables, p.163

[4]. Andrianarivo Irène RAHOBINIRINA, (2018) « Valorisation du CNSL de Madagascar via la synthèse : d’intermédiaire réactionnel et des dérivés éther acétiques », Docteur en Ressources des Ressources Naturelles Renouvelables,

[5]. Lubi, M. C. & Thachill, E. B. (2000).Des. Monomers Polym, 3, p.123

[6].Kubo, I.; Ochi, M.; Viera P. C. & Komatsu, S. (1993). - J. Agric. Food Chem., 41, p.1012

[7]. Trevisan, M. T. S.; Pfundstein, B.; Haubner, R.; Würtele, G.; Spiegelhalder, B.; Bartsch, H. & Owen, R. W. (2006).- Food Chem. Toxicol., 44, p.188

[8]. Morais, T. C.; Pinto, N. B.; Carvalho, K. M. M. B.; Rios, J. B.; Ricardo, N. M. P. S.; Trevisan, M. T. S.; Rao, V. S. & Santos F. A. (2010). - Chem-Bio. Interact, 183, p.264

[9]. Chelikani, R.; Kim, Y. H.; Yoon, D. Y. & Kim, D. S. (2009).  -Appl. Biochem. Biotechnol, 157, p.263

[10]. Francisco H. A. Rodrigues, José R. R. Souza, Nágila M. P. S. Ricardo, Judith P. A. Feitosa, (2011)Comparison Between Physico-Chemical Properties of the Technical Cashew Nut Shell Liquid (CNSL) and those Natural Extracted from Solvent and Pressing p. 156-160,

[11]. Setianto, W. B.; Yoshikawa, S.; Smith Jr., R. L.; Inomata, H.; Florusse, L. J. & Peters, C. J. - J. (2009). Supercrit. Fluids, 48, p.203

[12]. Kumar, P. P.; Paramashivappa, R.; Vithayathil, P. J.; Rao, P. V. S. & Rao, A. S. - J. (2002). Agric. Food Chem., 50, p.4705

[13]. Bastos, A.F., and Tubino, M. (2017). The Use of the Liquid from Cashew Nut Shells as an Antioxidant in Biodiesel. J Braz Chem Soc. 2017;28(5):747–55. J Braz Chem Soc 28, 747–755

[14]. Tagutchou, J.-P., and Naquin, P. (2012). Caractérisation et traitement thermochimique des coques d’anacarde en vue de leur valorisation énergétique dans les procédés de transformation artisanale de noix de cajou. Presented at the Colloque Eau, Déchets et Développement Durable, Agadir, Maroc, p.8

[15]. Miarintsoa Michaele Ranarijaona , Ny Aina Harivony Rambala Rakotomena, Mbolatiana Tovo Andrianjafy,Fenia Diane Ramiharimanana, Lydia Clarisse Herinirina, Niry Hasinandrianina Ramarosandratana, Benoit Briou, Pauline Fajardie, Patrick Mavingui, Estelle Métay, Voahangy Vestalys Ramanandraibe et Marc Lemaire (2021) Development of Sustainable Chemistry in Madagascar: Example of the Valuation of CNSL and the Use of Chromones as an Attractant for Mosquitoes

 [16]. Miarintsoa Michaele Ranarijaona Sandratriniaina Hermann Rafanoela, Lydia Clarisse Herinirina, Marie Christine Duclos, Alban Léon Lavaud, Catherine Goux-Henry, Estelle Métay, Voahangy Ramanandraibe Vestalys et Marc Lemaire, (2023) CNSL oxyacetic derivatives, ne bio-based binders for paint preparation.